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Phosphate reacts with calcium and magnesium forms less sticky, loose and non-adherent sludge instead of hard scale. The amount depends on the source of the water, be it surface water Mainly polyelectrolytes. The main purpose of internal treatment is to properly reduce hardness, sludge and remove oxygen from the feed water. Common type polyamide is an organic compound of high molecular weight. The carbon dioxide leaves the boiler with the steam and forms carbonic acid in the condensate system. 3. Sodium carbonate partially breaks down at high temperature to sodium hydroxide (caustic) and carbon dioxide. Condition. we have a high pressure boiler but we minimize our blowdown in relation to silica and pressure. Typical Boiler Water Treatment Configuration Historically, the choice of a pH sensor for boiler water monitoring has depended primarily on the conductivity of the boiler water. Boiler water Return to the work area and inspect for leaks. Each time you complete a water change you are physically removing Phosphates, and if you are replacing that water with RO/DI filtered For example, inorganic salts of orthophosphoric acids are sometimes added to tap water to protect the pipes, or demineralization systems may use phosphate salts for regeneration purposes, leaving phosphates in tap water. in two months time without blowdown, we have observed decreasing pH in the feed and boiler water even with 2-3 ppm phosphate. Monitoring of boiler water phosphate when using PC is necessary for the following reasons: The sodium-to-phosphate molar ratio determines the control point relative to the pH/PO4 High pressure boilers will generally need to be operated at the lower end of the PC, normally in the region designated PC(L). Boiler water oxygen scavengers do just that; they are products that can be added to the boiler water that help to remove oxygen and so reduce the problems associated with corrosion. Phosphate anti-scaling treatment is to add phosphate solution to keep a certain amount of phosphate radical in the boiler water. 2. The principle function of boiler is efficient heat transfer to the feed water. 3. In the internal treatment for silica, the boiler water alkalinity has to be kept high enough to hold the silica in solution. Sec-tion C illustrates the condition that actually develops. These operating conditions demand ultrahigh-purity water; this type of treatment is preferable since it does not contribute any solids to the boiler water. As for the internal treatment of boiler water, this process requires conditioning of impurities in the water, which means that the water is softened with softening chemicals such as sodium phosphate and soda ash. Often, sites pay less attention to the chemistry programs for these steam generators than to those for high-pressure units. Hydroxide. Like virtually all power companies, the utility treats its high-purity boiler water to a pH between 8.5 and 9. Directions (1.0 to 10.0 ppm) Fill test tube to 5ml mark with water sample to be tested. Therefore, the calcium ions in the boiler water will react with phosphate radical, the resulting basic calcium phosphate is a soft slag, which is easy to be removed with the boiler blowdown and wont adhere to the steel and turn into scale. tied up by dispersants and chelants and remain suspended in the boiler water where they can be removed by continuous surface or bottom blow down. Phosphates are often referred to as chelating or sequestering chemicals. Edited by kkala, 02 April 2010 - 12:04 AM. This produces unique wastage morphologies and characteristic corrosion products of NaFePO [sub 4]. It is important to refill the boiler with fresh water and inject the boiler chemical immediately to avoid your iron from rusting or corroding. The determination of equilibrium phosphate is done using a momentary super dosage of phosphate in the boiler, followed by interruption on phosphate dosage. Implementing the nitrite boiler chemical is very simple. An example of this combining of ions is the action between Calcium and Carbonate. This is referred to as phosphate corrosion. Naturally, the first thing pool owners do is go out and purchase a phosphate remover and add it into their pool. Test for Leaks. 5. These chemicals shove the pH toward the alkaline side of the scale. As we discussed above, chlorine does not react with phosphates in pool water. The chemical compound which forms is Calcium Carbonate. As with phosphate precipitation and chelant control programs, the use of these polymers with coordinated phosphate/pH treatment improves deposit control. Abstract. Phosphate is very stable at boiler water temperatures but extremely insoluble when it encounters calcium at high pH and high temperature. Simply charge the system with 800 to 1,500 ppm of sodium nitrite. Calcium phosphate scale is formed in water when minerals containing calcium ions combine with orthophosphate. For example, Caustic Soda, an alkaline, is added to neutralize CO3, carbonic acid. Now, you have a green pool AND white sediment at the bottom of your pool. So, it cannot lower the phosphate levels. Using trisodium phosphate for cleaning boiler is a good way. Rinse the bag when there is Phosguard is in the bag. In spite of that, first of mentioned boilers have been operating for 9 years with phosphate injection into deaerator drum, without problems reported (the other has not been yet installed). Phosphate anti-scaling treatment is to add phosphate solution to keep a certain amount of phosphate radical in the boiler water. PSI ENGG SYSTEMS P.LTD. If you notice they are getting high, the easiest first step to lowering the phosphate levels is to clean your tank and change the water. For many years the company used a specialized high-purity water sensor to measure the pH. This condition would, of course, result in a lower boiler water temperature T0. Iron, manganese, calcium and magnesium form stoichiometric (mole to mole) relationships with the sequestrant. Tap water. As you know, dissolved oxygen in boilers can cause a rapid corrosion known as pitting. With phosphates used as internal treatment, calcium reacts with the phosphate producing hydroxyapatite, which is much easier to condition than calcium sulfate. Figure 2. Left improperly treated silica and iron both can form harmful deposits. Note: In my opinion phosphates make a buffer solution to control pH of boiler water. Alkalinity is measured by titrating a water sample with a standard acid to a designated pH and is recorded as P, M, or T alkalinity. 3. However, boiler water temperature is fixed by the operating pressure, and operating conditions require that the same boiler water temperature be maintained as before the development of the deposit layer. Since calcium phosphate precipitates at higher temperatures, it tends to be more of a problem in heated pools or spas. In all cases it is the boiler water hydroxyl alkalinity, as measured by Excess chelant Chelant-based treatment is used in boilers operating below 1,000 psig. Secure long-term efficiency with the right approach to boiler water treatment and chemistry Monitor chemical injection practices closely during phosphate hideout and return conditions. You will reduce phosphates down to nothing pretty much. Normally each power station has their own practice; the values given are only a guideline as understood from various practices. Plant Service Bulletin: Boiler Water Phosphate Chemistry The coordinated phosphate treatment uses the feed of sodium phosphates in maintaining the boiler water pH. where Ammonia used for boosting PH in condensate(feed water). Blends of sodium nitrite with a P Indicator chemical make it even easier. A sequestering agent is a compound that will form a water soluble, stable metal complex without precipitation. When the concentration of phosphate in the boiler water is too high, phosphate will react with boiler scale forming iron and iron sodium phosphates or precipitate to form a solid phase on the hot boiler tube surfaces and elsewhere. You can fit 2 bags in there. The first thing pool owners should focus on is removing the algae. Some boiler-tube failures attributed to caustic gouging actually have been caused by reaction of sodium phosphate species with boiler tube steel, boiler tube oxides, or both. For high silica waters in high pressure steam boilers, it is important to maintain a 3:1 total alkalinity to silica ratio to prevent silica from plating on your boiler tubes. our treatment if ammonia and hydrazine at the feedwater and TSP for the 3. Sulfite reacts with oxygen and produces sulfate. Test this solution with your test kit for; iron, magnesium hardness, calcium hardness, phosphate, sulfate and copper. Boiler feedwater can be protected from corrosive conditions through coordinated phosphate/pH control treatment. Sodium sulfite is often added to boiler water to assist with the chemical removal of any dissolved oxygen content. HCO 3. When the steam becomes condensate, the carbon dioxide becomes carbonic acid, which is corrosive to the steam lines. It is necessary to maintain phosphate levels below 100 ppb. it helps to convert the calcium hard salts to soft sludge. Q. I would like to add on his question in relation to our plant. This is the only way chlorine can be used to lower phosphate in a pool. It does not directly lower phosphate levels in the pool. Careful RO feedwater analysis is critical for proper And finally on section 6 we will summarize our treatment if ammonia and hydrazine at the feedwater and TSP for the The phosphate and pH are given based on Co-ordinate phosphate treatment so as to prevent the presence of free hydroxide in the boiler water. How to reduce iron and / or copper corrosion on condensate and boiler feed water section in order to reduce the metal load to boiler will be discussed on section 4. water. TSP usually comes in the form of an odorless dry powder that must be thoroughly mixed into hot water to form a mostly clear solution, though slightly cloudy. FW=MW+CW. In high pressure steam plants, small amounts of alkalizing agents are added to condensate, feedwater and boiler water to raise the pH to reduce corrosion. The boiler feed water should be treated legitimately to avoid scale, corrosion of the boiler system. We all know that if PH is below 7 the solution is acidic and above 7 its alkaline. Sulfite is a very important chemical used to scavenge oxygen in steam boilers. Then, add about 2 tablespoons of leave-in conditioner to soften the weave. During chemical precipitation, aluminum, calcium, or iron can be used as multivalent metal ions to form a phosphorous precipitate, Turn the faucets off after they have stopped sputtering. This method is also a great way to increase the calcium levels in your pool. Ideally the feed water should be in the range of pH 8.5 9. P alkalinity is titrated with p henolphthalein to pH 8.3, M alkalinity with m ethyl orange indicator to pH 4.6, and T alkalinity with t otal alkalinity indicator to pH 4.5. The occurrence of scale problems will seriously affect the working efficiency of boiler. Phosphate Hideout. After the boiler is used for a period of time, due to the high evaporation intensity as well, the calcium and magnesium ions in the boiler water will evaporate and concentrate forming scale. Generally. Acid Attack. For pressure range 166-205 silica in boiler water to be kept below 0.10 ppm. h 1 per degree C. This scaling is mainly caused by the presence of calcium salts (carbonates or sulphates) in the water. They are normally found in boilers employing a phosphate internal treatment. Algae removal methods like algaecides or shocking also help to remove phosphates. Caustic treatment is typically used in LP boilers. Regardless, if the boiler system is new or old a ideally a chemical pot feeder should be used to inject the hot water boiler chemical into the system. Phosphate buffers the boiler water, reducing the chance of large pH swings Boiler deposits reduce overall operating efficiency resulting in higher fuel consumption. 1. When the pH reaches 10, corrosion becomes impossible. This program can be used in boilers operating above 2,500 psig, but below supercritical pressures. Phosphate hideout in HP boilers can be prevented by switching to EPT. Caustic treatment is typically used in LP boilers. Chelant-based treatment is used in boilers operating below 1,000 psig. Excess chelant can attack clean boiler surfaces. BLOWDOWN WATER (BW) - The part of the water which is purely drained in order to remove impurities to an acceptable level. in high-pressure boilers when Sufficient disodium phosphate must be available to combine with all of the free caustic in order to form trisodium phosphate. Whilst the boiler water conductivity is converted to a resistance through the probe, it cannot be Coral Passion said: Phosguard and GFO are two options but you will need to actively replace the media every two to four weeks. Sodium phosphate causes the hardness to precipitate to the bottom of the boiler where it can be blown down. Sodium phosphate compounds are added to boiler water to control the pH and to react with any hardness compounds that might enter due A proper water treatment program is essential. Oxygen scavengers There are several types of oxygen scavenger: organic and inorganic, the difference being that inorganic products add dissolved solids to the water. A typical phosphate residual in boiler water is between 10 to 20 ppm of phosphate or 7 ppm of phosphate per 1 ppm of hardness. 2006. Sulfite is a very important chemical used to scavenge oxygen in steam boilers. Changing the water in your tank often will help keep the phosphate levels low. 11 Dec 2012 Exact dosage rate depends on pH variation of water in drum. Let it boil for about 10 minutes, then use a pair Q. I would like to add on his question in relation to our plant. pH Related Corrosion. feed water has to alkalized to PH of 9 or little high(high alkalized solution causes caustic corrosion), to reduce oxidation and to support the formation of a stable layer of Magnetite on water side surface of boiler, protecting metal from further corrosion. Cl . Slowly open the main water line, and allow the faucets to run until all of the air is bled from the lines. They are the preferred reaction product when using a residual phosphate treatment on high hardness feed water. A boiler is a closed device used largely in various industries, business, and modern procedures to generate steam by applying heat energy to water at a particular pressure. Depending on the boiler steam pressure, scale control is achieved by a combination of internal treatment and improvement in the quality of feed water to the boiler. Chemical precipitation, also known as a chemical phosphorus removal or primary phosphorus removal, can remove inorganic phosphates from water by adding a coagulant into the wastewater. the sludge is higher in weight ,so it comes to the bottom of the drum . Limit or eliminate phosphate feed during hideout then it is removed by CBD. Chemical Precipitation. If youve already experienced this, you already know that this wont solve your green pool. Phosphates can be dosed continuously or intermittently. These salts are less soluble when hot than when cold or when there is an excessively high level of silica in relation to the alkalinity of the water in the boiler. Now add . reaction product when using a residual phosphate treatment on high hardness feed water. Metal transport in boiler or how to minimize boiler tube fouling due to metal load will be the main fact on section 5 of this paper. Managing Phosphorus with Natures Pond: Natures Pond three-step program is designed to fight phosphorus and nutrient pollution in ponds. What removes phosphates from pool water? Corrosion. Start by bringing a large pot of water to a boil and then add a teaspoon of olive or coconut oil to help moisturize your weave. The safe pH range for steam boilers is between 8.5pH & 12.7pH, whilst the recommended level is between 10.5pH & 12.0pH. 40B Knasty said: Buy a bottle of Phosguard. There are four main ways to help lower the Phosphate level in your aquarium: 1. A bag that will hold Phosguard. In order to successfully remove dissolved oxygen from the system, make sure that sulfite levels are kept above the minimum of 20 ppm. 4. A relatively high frequency (for example 1 000 Hz) is necessary to avoid polarization at the high conductivities of boiler water. Filtering the water may help as well. This product works great with testing boiler chemical treatment programs like ChemWorld 1595. The sodium that was attached to the bicarbonate reacts to form alkalinity. in two months time without blowdown, we have observed decreasing pH in the feed and boiler water even with 2-3 ppm phosphate. Carbonate. Power (15-Sep-04) In lower-pressure industrial boilers phosphate treatment relies on combinations of disodium and trisodium phosphate to produce in the boiler . Will keep oil in an emulsion. Prevents the precipitated sodium based particles forming soft scales. Thats what makes chemical drain cleaners safe for pipes. Boiler water oxygen scavengers do just that; they are products that can be added to the boiler water that help to remove oxygen and so reduce the problems associated with corrosion. If the results are off the scale, dilute the sample again by. Control is achieved through feed of the proper type of phosphate to either raise or lower the pH while maintaining the proper phosphate level. As operating pressures have increased, the frequency of corrosion-related failures in phosphate-treated boilers has also increased. In the internal treatment for silica, the boiler water alkalinity has to be kept high enough to hold the silica in solution. Phosphates Phosphates are used to reduce the level of scale deposition within the boiler. CO 3 . one mole of trisodium phosphate will increase boiler water pH Correcting the dosage of phosphate if the Although high pressure boilers and the. High-Pressure Steam Cycle and Boiler Water Treatment High Pressure Boilers As trisodium phosphate hydrolyzes in the water it produces a hydroxyl ion (OH) boiler water treatment. Effects. Chemical pot feeder come in sizes from 2 to 12 gallons. But it can lower it by preventing algae growth in the pool. Antifoams. Many plants use low-pressure boilers to produce process steam for various applications, including heat for chemical reactors, evaporators, building spaces, etc. PHOSPHATE PURPOSE Guardian CSC. Buy one of these Tetra 10 filters and place that in your tank. pH is controlled by either removing water impurities or adding other chemicals to neutralize the condition. And even if you fix the leaks in the system, you still have to keep an eye on the pH of the water because many people add chemicals to their boilers to avoid corrosion. Alkalinity in steam-generating boilers is a problem because under heat the alkalinity breaks down to carbon dioxide, which passes with the steam. Water contains alkalinity. High temperatures in the boiler water reduce the solubility of calcium sulphate and tend to make it precipitate out directly on the boiler metal as scale. Also, keeping the tank clean helps keep the phosphate levels down. Trisodium phosphate, commonly called TSP, is a packaged, blended cleaning product consisting of 75 to 80 percent trisodium phosphate and 20 to 25 percent sodium carbonate. Falling into the area on the co-ordinated phosphate pH diagram below the lower dotted line means that normal treatment to bring back into the target area is impossible. Conductivity can range from 7,000 S/cm in a low-pressure industrial boiler to under 10 S/cm in a high-pressure boiler in a steam power plant. Boiler water can be treated with several agents, including a phosphate/polymer combination, polymers alone, and (rarely) chelating agents. The type as well as the quantity of suspended solids can affect carryover. reduce the stability of water film around steam bubble and cause it to collapse. When the boiler water pH drops below about 8.5, a corrosion called acid attack can occur. Porous metal oxide deposits also permit the development of high boiler water concentrations. Where an economiser or feed water per-heater is used they Generally it is desirable to have a slightly high pH for boiler feed water. The larger the water system, the larger the preferred unit (saves time refilling the unit). For boiler water PH is maintained between 11-11.8 and that of feed water between 7-9. Like virtually all power companies, the utility treats its high-purity boiler water to a pH between 8.5 and 9. FEED WATER (FW) - Feed water is the total of condensate water and make up water which is fed to the boiler for production of steam. For many years the company used a specialized high-purity water sensor to measure the pH. An oxygen scavenger is a chemical that consumes oxygen through an oxidation-reduction (redox) reaction. OH . Under boiler water conditions, bicarbonate decomposes first to carbonate and then to carbon dioxide . Make up water commensurates for Blow down loss. ASME Phosphate Treatment Guidelines (boilers below 600 PSIG) OH-Alkalinity 100-600ppm Phosphate 30-50ppm Silica 200 - (0.25x Boiler Oxygen scavengers There are several types of oxygen scavenger: organic and inorganic, the difference being that inorganic products add dissolved solids to the water. putting 10 ml of the solution into 90 ml of DI water. To minimize the iron deposition in high-pressure (1000-1750 psig) boilers, specific polymers have been designed to disperse the iron and keep it in the bulk water. With phosphates used as internal treatment, calcium reacts with the phosphate producing hydroxyapatite, which is much easier to condition than calcium sulfate. the water must be kept alkaline. It prevents scale formation from low remaining levels of hardness which may have escaped treatment. Abstract. Water flows into the deposit and heat applied to the tube causes the water to evaporate, leaving a very concentrated solution. Dry off the pipes and the new regulator. Phosphate RX is a good soultion to instantly drop phosphates but there is more risk involved. Generally the Phosphate dozing is done in the drum of the boiler. Phosphates can get into the aquarium with water. Water Changes & Vacuuming of Sand Bed (Detritus Removal) As explained earlier, your aquarium is an enclosed bio-system that will build up Phosphates over time. we have a high pressure boiler but we minimize our blowdown in relation to silica and pressure. Sufficient pretreatment to remove suspended solids ahead of RO membranes and a well-designed chemical treatment program to minimize scale formation are important to successful RO unit operation. Depending on the boiler steam pressure, scale control is achieved by a combination of internal treatment and improvement in the quality of feed water to the boiler. Boiler Feedwater A key to protecting the boiler system is to treat the boiler feedwater entering the system. Low water treatment costs are necessary. An oxygen scavenger is a chemical that consumes oxygen through an oxidation-reduction (redox) reaction. Evaluate the loss of phosphate from the system by material balance calculations. Figure 1: Iron oxide deposits in boiler tubes leading to tube bursts with the typical fishmouth openings. For medium-pressure units, phosphate treatment of the boiler water is still the preferred choice. The detailed chemistry of phosphate treatment programs has been well documented and does not need to be recounted here. However, the following discussion illustrates the importance of good water chemistry monitoring. This sludge remains in the boiler water in suspended condition and then, removed from the boiler through blow down Other than TSP, disodium phosphate (Na2HPO4) and monosodium phosphate (NaH2PO4) are used in boiler for dosing. this is one of the way of avoiding corrosion in Boiler. The result in pools and spas is an insoluble white scale on the surfaces of pools and equipment. III.B.2 Precipitation. Controlling the pH levels and conductivity of the feed water in your boiler will help you reduce the possibility of boiler water carryover into your steam system, eliminate the possibility of overfeeding chemicals, reduce the amount of time that you spend testing the system, and eliminate the need to regularly remove highly conductive water, which causes you Frequent shocking also helps to keep your pool clean while preventing algae growth. 1 PHOSPHATE PURPOSE: To remove boiler water calcium as sludge instead of hard scale. 2006. Ultimately there is a reason your phosphate are high and it will most likely be due to over stocking or over feeding. As you know, dissolved oxygen in boilers can cause a rapid corrosion known as pitting. Water evaporating in the boiler causes impurities to concentrate. Sulfite reacts with oxygen and produces sulfate. Other impurities which will affect the boiler water treatment control include Copper, Iron Oxides, oil and dissolved gases. Controlling the PH of water is the first step towards boiler treatment. Utilities operating drum-type boilers on phosphate base treatment should: 1. Since calcium carbonate is relatively insoluble it tends to come out of solution.