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This is due to a build-up of alkaline and other minerals in your water. 128 oz. 2-3 times a year, add a non-toxic cleaner (like BioClean Hard Water Stain Remover) to your home care rotation. Enter code at checkout to save. A Brush for Every Toilet Our range of cleaning products are non chemical and non acidic. Act quickly - the faster you can treat the stain with salt and water paste, the less time is has to set into the fibers. Use a small brush to scrub the mixture into the stained area.